Functional Polymers by Post-Polymerization Modification

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Concepts, Guidelines and Applications

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ISBN: 9783527331154 Category:

In modern polymer science a variety of polymerization methods for the direct synthesis of polymers bearing functional groups are known. However, there is still a large number of functional groups that may either completely prevent polymerization or lead to side reactions. Post-polymerization modification, also known as polymer-analogous modification, is an alternative approach to overcome these limitations. It is based on the polymerization of monomers with functional groups that are inert towards the polymerization conditions but allow a quantitative conversion in a subsequent reaction step yielding a broad range of other functional groups. Thus, diverse libraries of functional polymers with identical average degrees of polymerization but variable side chain functionality may easily be generated.<br /><br />Filling the gap for a book dealing with synthetic strategies and recent developments, this volume provides a comprehensive and up-to-date overview of the field of post-polymerization modification. <br /><br />As such, the international team of expert authors covers a wide range of topics, including new synthetic techniques utilizing different reactive groups for post-polymerization modifications with examples ranging from modification of biomimetic and biological polymers to modification of surfaces. <br /><br />With its guidelines this is an indispensable and interdisciplinary reference for scientists working in both academic and industrial polymer research.